Synthese von captopril

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Go to old article view. By continuing to browse this site you agree to us using cookies as described in About Cookies Remove maintenance message. Abstract The 1,3-dipolar cycloaddition of the C - t -butyloxycarbonyl- N -mannosyl-nitrone 5formed in situ from the partially protected D -mannose-oxime 3 and the glyoxylate 4to ethylene gave preferentially the 3 S - N -glycosyl-isoxazolidine 6 which was transformed into the 3-isoxazolidine-carboxylate L oxaproline ester 12 and into some derivatives thereof.

Number of times cited: Close article support pane. The 1,3-dipolar cycloaddition of the C - t -butyloxycarbonyl- N -mannosyl-nitrone 5formed in situ from the partially protected D -mannose-oxime 3 and the glyoxylate 4to ethylene gave preferentially the 3 S - N -glycosyl-isoxazolidine 6 which was transformed into the 3-isoxazolidine-carboxylate L oxaproline ester 12 and into some derivatives thereof.

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Articles related to the one you are viewing Please enable Javascript to view the related content of this article. View all 33 citations. The D oxaproline ester was obtained from the corresponding N -ribosyl-nitrone The S -configuration of 12 was proved by chemical correlation with a derivative of L -asparagine. CrimminsAgnes S. KozhushkovDmitrii S.

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